An easy-to-break carrying device for a volatile (30) includes a packaging case (10), a sealing film (13), a destruction assembly (20), and a permeable film (14). The packaging case (10) has a first accommodating space (11) for receiving the volatile (30) and a second accommodating space (12) connecting to the first accommodating space (11) having an opening. The sealing film (13) covers the opening of the first accommodating space (11). The destruction assembly (20) is disposed in the second accommodating space (12) and located above the sealing film (13). The destruction assembly (20) has a housing body (21), two extending plates (22), and a plurality of piercing portions (23). The permeable film (14) is disposed at the opening of the second accommodating space (12) of the housing body (21) and covers above the destruction assembly (20).