The present invention provides a grainy material which comprises the following components: (i) at least 50wt% of solid water-insoluble mixed metal compound when the weight of the grainy material is taken as a reference, the mixed metal compound can combine with microcosmic salt of the formula (I): M1-xMx(OH)2Ay*zH2O (I), in the formula M is magnesium, calcium, lanthanum and cerium M is iron at least A is at least one n-valence anion x is the summation of ny 0