The present invention relates to a film forming complex and a cosmetic composition comprising this complex, both with excellent peel-off properties. The film forming complex comprises two natural film formers which are Hydrolyzed Corn Starch (trade name Asensa NFF11 E) and Pullulan (trade name Pullulan). Both, the complex of the invention and the cosmetic composition comprising the complex do not contain polyvinyl alcohol, alginates, alginic acid, polyurethane and ethanol. If the film forming complex or the cosmetic composition of the invention is applied to the skin a thin film mask with excellent coverage is formed within a drying time of less than 10 to 15 minutes. Following treatment, the mask will peel off easily in a single piece without pain. It does not cause redness and leaves a comfortable, smooth and pleasant feel on the skin.