PROBLEM TO BE SOLVED: To provide a pretreating material and an adhesive material for dental use, which is compounded with a polymerizable monomer containing an acidic group and a filler eluting a polyvalent metal ion, and is essentially free from an organic solvent and is suppressed in gelatinization, although it is preserved in a one-package state.SOLUTION: The one-package pretreating material for dental use is produced by mixing (A) 100 pts.mass of polymerizable monomers containing &ge5 mass% polymerizable monomer having an acidic group and &ge55 mass% water-soluble polymerizable monomer free from acidic group and having hydroxyl group, (B) a filler eluting polyvalent metal ion and compounded at a rate of 0.4-2.0 (meq) based on 1 g of the component (A), (C) 3-30 pts.mass of water and (D) 2-20 pts.mass of a silica filler having a specific surface area of &ge50 m2/g. The one-package adhesive agent for dental use may further contain (E) a photopolymerization catalyst in addition to the above components.COPYRIGHT: (C)2009,JPO&INPIT【課題】酸性基含有重合性単量体と多価金属イオン溶出性フィラーとが配合されてなる歯科用前処理材および接着材において、1液で保存される形態でありながら、実質的に有機溶媒を含まずにゲル化が抑制された歯科用前処理材および接着材の提供。【解決手段】(A)酸性基含有重合性単量体を5質量%以上、且つ酸性基を有さず水酸基を有する水溶性重合性単量体を55質量%以上含む重合性単量体を100質量部、(B)(A)成分1g当たり0.4~2.0(meq)となるように配合された、多価金属イオン溶出性フィラー、(C)水を3~30質量部、(D)50m2/g以上の比表面積を有するシリカ系フィラー2~20質量部からなる各成分を混合してなる1液型歯科用前処理材。さらに(E)光重合触媒を含む1液型歯科用接着剤。【選択図】なし