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КОМПЛЕКСНОЕ МЕТАЛЛ-САЛЕНОВОЕ СОЕДИНЕНИЕ, ОБЛАДАЮЩЕЕ СОБСТВЕННЫМ МАГНЕТИЗМОМ
专利权人:
АйЭйчАй КОРПОРЕЙШН (JP)
发明人:
ИСИКАВА Есихиро (JP),ЕГУТИ Харуки (JP)
申请号:
RU2014106993/04
公开号:
RU2014106993A
申请日:
2012.05.14
申请国别(地区):
RU
年份:
2015
代理人:
摘要:
1. New salen-metal complex compound having own magnetism represented by the following formula (I) (I) wherein each of X and Y represents a five-membered ring structure containing a coordination bond between N and M or six-membered ring structure, wherein M a divalent metal selected from Fe, Cr, Mn, Co, Ni, Mo, Ru, Rh, Pd, W, Re, Os, Ir, Pt, Nd, Sm, Eu or Gd, Never attempt, both X and Y represent a five-membered ring structure, b and g are absent, then formula (i) is any of structures (i) - (iv) :( i) ah each represents hydrogen or any of the following groups (a) - (G) and - C (= O) m (where m is hydrogen or any of the following groups (a) - (G)) (ii) each of (c, d) and (f, e) forms part of a heterocyclic structure and forms a fused structure represented by formula (I) and a heterocyclic structure, each of a, b, g and h represents hydrogen or any of the following groups (a) - (G), and -C (= O) m (where m is hydrogen or any of the following groups (a) - (G)), is a heterocyclic structure from any of the three to seven-membered ring structures include furan, thiophene, pyrrole, pyrrolidine, pyrazole, pyrazolone, imidazole, 2-izoimidazol, oxazole, isoxazole, thiazole, imidazole, imidazolidine, oxazoline, oxazolidine, 1,2-pyran, thiazine, pyridine, pyridazine, pyrimidine, pyrazine, ortoksadin, oxazine, piperidine, piperazine, triazine, morpholine or dioxane, ibokovaya chain represents a heterocyclic structure halogen, -R, -OR (where R represents one functional group selected from a hydrocarbon group comprising a methyl group) or hydrogen (iii) each of (c, d) and (f, e) of1. Новое металл-саленовое комплексное соединение, обладающее собственным магнетизмом, представленное следующей формулой (I)(I)где каждый из X и Y представляет собой пятичленную кольцевую структуру, содержащую координационную связь между N и М, или шестичленную кольцевую структуру,где М представляет собой двухвалентный металл, выбранный из Fe, Cr, Mn, Co, Ni, Мо, Ru, Rh, Pd, W, Re, Os, Ir, Pt, Nd, Sm, Eu и
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