Provided is a reticulated polymer, which is prepared by reacting a prepolymer having an isocyanate-group at distal ends with at least one hydroxyl group and at least one reactant having an unsaturated group. The prepolymer is prepared through polymerization of starting materials in the presence of catalysts. The reactant is prepared through reaction of mixed materials in the presence of catalysts. In this invention also provides a composition for manufacturing biomedical devices, and biomedical devices manufactured by a molding process of the composition. The invented reticulated polymer has a special structure design that can easily form the composition, which enable the subsequently manufactured biomedical devices meet the actual application requirements.一種網狀高分子,是由末端為異氰酸酯基的預聚合物與具有至少一個羥基及至少一個不飽和基的反應物進行反應所製得。該預聚合物是由起始材料於催化劑存在下進行聚合反應所得。該反應物是由混合材於催化劑存在下進行反應所得。本發明另提供一種用於製作生醫裝置的組成物,及由其進行模製而得的生醫裝置。本發明網狀高分子具有特殊結構設計而易於形成該組成物,更讓後續製得的生醫裝置能符合實際應用需求。