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METHOD OF PRODUCING ADDITIONALLY CROSS-LINKED WATER-ABSORBING POLYMER PARTICLES WITH HIGH ABSORPTION BY POLYMERISING DROPLETS OF SOLUTION
专利权人:
BASF SE
发明人:
ShTJuVEN Uve (DE),ШТЮВЕН Уве (DE),VAJSMANTEL' Mattias (DE),ВАЙСМАНТЕЛЬ Маттиас (DE),KhAJDE Vil'frid (DE),ХАЙДЕ Вильфрид (DE),KRJuGER Marko (DE),КРЮГЕР Марко (DE),ZAJDL' Fol'ker (DE),ЗАЙДЛЬ Фолькер (DE,SHTJUVEN UVE,ШТЮВЕН Уве,VAJSMANTEL MATTIAS,ВАЙСМАНТЕЛЬ Маттиас,KHAJDE VILFRID,ХАЙДЕ Вильфрид,KRJUGER MARKO,КРЮГЕР Марко,ZAJDL FOLKER,ЗАЙДЛЬ Фолькер,BLJAJ SHTEFAN,БЛЯЙ Штефан,LESH DENNIS,ЛЕШ Деннис,FUN
申请号:
RU2009105484/04
公开号:
RU0002480481C2
申请日:
2007.07.09
申请国别(地区):
RU
年份:
2013
代理人:
摘要:
FIELD: chemistry.SUBSTANCE: described are water-absorbing polymer particles with centrifugal retention capacity (CRC) of at least 20 g/g and absorptionm under a load of 4.83 kPa (AUL0.7psi), which satisfy the condition AUL0.7psi≥-0.017CRC2+1.5CRC-6. The polymer particles have average sphericity of at least 0.84 and hydrophobic solvent content of less than 0.005 wt %. Also described are water-absorbing polymer particles with average sphericity of at least 0.84, hydrophobic solvent content of less than 0.005 wt %, and CRC of at least 20 g/g and free swell rate (FSR) which satisfies the condition FSR≥ -0.00082 CRC2+0.07CRC-0.95. Described is a method of obtaining said particles by polymerising droplets of a monomer solution which contains a) at least one at least one ethylenically unsaturated monomer having at least one acid group, b) at least one cross-linking agent, c) at least one initiator, d) water in the gas phase surrounding the droplets, the obtained polymer particles being additionally cross-linked, wherein content of solid substance of the monomer solution is at least 35 wt %, and the monomer solution is added in droplets to the gas phase to form a monodispersion droplet chain, and wherein the polymer particles have mean diameter of at least 150 mcm, wherein the process is carried out, if necessary, in the presence of a hydrophobic solvent. Use of said polymer particles to obtain sanitary and hygiene products is also described.EFFECT: obtaining water-absorbing polymer particles with an improved profile of characteristics, high permeability, high centrifugal retention capacity, high absorption under load and high free swell rate.27 cl, 1 dwg, 3 tbl, 9 exНастоящее изобретение относится к способу получения дополнительно сшитых водопоглощающих полимерных частиц. Описаны водопоглощающие полимерные частицы с емкостью центрифугального удержания (CRC), по меньшей мере, 20 г/г и поглощением под давлением 4,83 кПа (AUL0.7psi), которое выполняет условие AUL0.7psi≥-0,0
来源网站:
中国工程科技知识中心
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http://www.ckcest.cn/home/

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