The present invention relates to a novel herbicidal composition comprising a herbicidal active ingredient combination of prosulfocarb and at least one other herbicide selected from flufenacet, mefenacet, naproanilide, napropamide, diphenamid, butachlor, acetochlor, dimethenamid, dimethachlor, alachlor, metolachlor, S-metolachlor, propisochlor, pethoxamid, metazachlor, thenylchlor, propachlor, fentrazamide, anilofos, piperophos and cafenstrole. Each combination is suitable for the selective control of undesired vegetation like weeds (grasses and broad-leaved weeds) in crops of useful plants, for example in crops of rice, cereals and maize.