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Use of specific bis(biphenyl)triazine derivatives and mixtures thereof as UV absorbers
专利权人:
Bernd Herzog;Barbara Wagner
发明人:
Barbara Wagner,Bernd Herzog
申请号:
US13822014
公开号:
US20130164231A1
申请日:
2011.09.09
申请国别(地区):
US
年份:
2013
代理人:
摘要:
Disclosed is the use of mixtures comprising at least 2 structurally different bis(biphenyl)triazine derivatives of formula (1) wherein X is hydrogen; C1-C50alkyl which may be uninterrupted or interrupted by one or more oxygen atoms and/or substituted by one or more R8 groups; C3-C12-cycloalkyl which is substituted by R8; —CH((CH2)p—R8)—CO—O—(CH2)m—R9; —CH((CH2)p—R8)—CO—(NR10)—(CH2)m—R9; —CO—O—(CH2)p—Ra; —CH2—CH(—O(CO)—R8)—R9; —CO—(NR10)—(Ch2)p—Ra; C6-C20aryl; allyl; C4-C50alkenyl which is uninterrupted or is interrupted by one or more oxygen atoms; C3-C12cycloalkyl which is uninterrupted or interrupted by one or more oxygen atoms; C3-C20alkynyl; C6-C12cycloalkynyl; R1 is hydrogen; unsubstituted or substituted unsubstituted or substituted C3-C12cycloalkyl; unsubstituted or substituted C6-C20aryl; unsubstituted or substituted C2-C20alkenyl; OR7; OH; SR8; SOR7; SO2R7; SO2H; SO3M; or a radical of the formula (c); R2, R3, R4, R5 and R6 independently of one another are hydrogen; hydroxyl; —CN; substituted or unsubstituted C1-C20alkyl; unsubstituted or substituted C3-C12-cycloalkyl; unsubstituted or substituted C1-C18alkoxy; unsubstituted or substituted C4-C20cycloalkoxy; C7-C20phenylalkyl; halogen; halo-C1-C5alkyl; sulfonyl; carboxyl; acylamino; acyloxy; C1-C12alkoxycarbonyl; aminocarbonyl; R7 is substituted or unsubstituted C1-C18alkyl; unsubstituted or substituted C3-C12-cycloalkyl; unsubstituted or substituted C6-C20aryl; unsubstituted or substituted C2-C20alkenyl; or C7-C20phenylalkyl; M is alkali metal; R8 and R9 independently of one another are Rx if attached to a carbon atom and are Ry if attached to an oxygen atom; p is 0 to 20; m is 0 to 20; Rx is hydrogen; hydroxyl; C1-C30alkyl; C3-C12cycloalkyl; C1-C30alkoxy; C3-C12cycloalkoxy; C3-C12-cycloalkyl or C3-C12cycloalkoxy which is interrupted by one or more oxygen atoms; C6-C12aryl; hetero-C3-C12aryl; —ORz; NHRz; Rz; CONR10R11; SO3H; SO3M; OSO3H2; allyl, C2-C30alkenyl; C4-C12-cycloalkenyl which is uninterrupted or in
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