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METHOD FOR PRODUCING RANDOM RADICAL COPOLYMERS AND OBTAINABLE ACTIVE SUBSTANCE COMPOSITIONS
专利权人:
BASF SE
发明人:
Turk, Holger,Тюрк Хольгер,Dieleman, Cedric,Ділеман Седрік,Bohrmann, Hans-Gunter,Борманн Ханс-Гюнтер,Koltzenburg, Sebastian,Кольценбург Себастіан
申请号:
UA201108290
公开号:
UA106218C2
申请日:
2009.11.30
申请国别(地区):
UA
年份:
2014
代理人:
摘要:
The invention relates to a method for producing random radical copolymers, characterized by the following steps: a) dissolving by heating a) at least one olefinically unsaturated sulfonic acid of formula (I) wherein n is 0 to 10 X represents O or NR5 R1 represents hydrogen or methyl R2, R3 independently represent hydrogen or C1 to C6 alkyl and R5 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, wherein the aryl groups can be mono- or polysubstituted, the salts thereof or mixtures of acid and salts and b) at least two structurally distinct olefinically unsaturated monomers of formula (II), wherein Y represents O or NR7 R5 represents hydrogen or methyl R6 represents alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylammoaryl and R7 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, and c) optionally one or more olefinically unsaturated monomers which can be structurally distinct from components (a) and (b), and at least one initiator, either (i) in a solvent mixture which contains water and a solvent having a boiling point below 140 °C and being soluble in water, or (ii) in one or more pure alcohols, and polymerizing said mixture in solution, the copolymer formed also remaining dissolved. The copolymers obtainable according to the above method are suitable as formulation adjuvants in agrochemical active ingredient compositions. EMBED ISISServer (I) EMBED ISISServer (II)Спосіб одержання статистичних радикальних співполімерів, у якомуа) щонайменше одну олефінову ненасичену сульфонову кислоту формули (І), (I)деn дорівнює 0-10X означає О або NRRозначає водень або метилR, Rнезалежно один від одного означають водень або С-С-алкіл іRозначає водень, алкі
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