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Method for manufacturing methylmercaptopropionaldehyde and methionine using renewable raw materials
专利权人:
Jean-François Devaux
发明人:
Jean-François Devaux,Jean-Luc Dubois
申请号:
US13128927
公开号:
US08735631B2
申请日:
2009.11.19
申请国别(地区):
US
年份:
2014
代理人:
摘要:
The present invention relates to a method for manufacturing methylmercaptopropionaldehyde (MMP) including at least the following steps: (a) dehydrating glycerol to acrolein from an aqueous solution of glycerol in the presence of an acid catalyst (b) purifying the aqueous flux from step (a) to obtain a flux of acrolein containing at least 15 wt % of water relative to the acrolein (c) causing a reaction of the acrolein flux obtained in step (b) with methylmercaptan in the presence of a catalyst (d) optionally purifying the product obtained in step (c). The method of the invention can also include a reaction of the product obtained in step (c) or (d) with hydrocyanic acid, or sodium cyanide during a step (e) followed by a subsequent transformation to produce methionine or methionine hydroxyanalogue, which can then optionally be purified. The additional use of methylmercaptan and/or hydrocyanic acid derived from biomass as raw materials in the method according to the invention makes it possible to obtain MMP, methionine or methionine hydroxyanalogue made up of 100% organic carbon from renewable sources.
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中国工程科技知识中心
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