The present invention provides a process for demineralization and desulphurization of coal. The process of demineralization and desulphurization of coal is carried out by using aqueous sodium carbonate and acid solutions, at atmospheric pressure and at relatively low temperature. The process for demineralization and desulphurization of high sulphur sub bituminous coal using aqueous sodium carbonate solution (2-16% w/v) is less corrosive in comparison to other alkalies like sodium hydroxide, potassium hydroxide etc. used by previous workers.