A process comprising reacting the XVIIb molecule (where R4 is H) to form the XXV molecule (where R4 is H), then reacting the XXV molecule with XIXc to form the XXVI molecule (where R4 is H), then, react the XXVI molecule to form the XXVII molecule ** Formula ** where: (a) X is N or CR8； (b) R1 is H, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, C2-C6 alkenyloxy substituted or unsubstituted, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR9, C (>； = X1) R9, C (>； = X1) OR9, C (>； = X1) N (R9) 2, N (R9) 2, N (R9) C (>； = X1) R9, SR9, S (O) nOR9 or R9S ( O) nR9, wherein each said R1, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2 haloalkenyl -C6, C1-C6 haloalkyloxy, C2-C6 haloalkenyloxy, C3-C10 cycloalkyl, C3-C10 cycloalkenyl, C3-C10 halocycloalkyl, C3-C10 halocycloalkenyl, OR9, S (O) nOR9, C6-C20 aryl or C1-C20 heterocyclyl , (each of which may be substituted, may optionally be substituted with R9)； (c) R2 is H, F, Cl, Br, I, CN, NO2, substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C2-C6 alkenyl, substituted or unsubstituted C1-C6 alkoxy, C2-C6 alkenyloxy substituted or unsubstituted, substituted or unsubstituted C3-C10 cycloalkyl, substituted or unsubstituted C3-C10 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C1-C20 heterocyclyl, OR9, C (>； = X1) R9 , C (>； = X1) OR9, C (>； = X1) N (R9) 2, N (R9) 2, N (R9) C (>； = X1) R9, SR9, S (O) nOR9 or R9S (O ) nR9, wherein each said R2, which is substituted, has one or more substituents selected from F, Cl, Br, I, CN, NO2, C1-C6 alkyl, C2-C6 alkenyl, C1-C6 haloalkyl, C2- haloalkenyl C6, C1-C6 haloalkyloxy, C2-C6 halo
