The present invention relates to a silicone fluid comprising a glycoside group and oil in water emulsions composition of silicone fluid used in hair care compositions for hair care applications, process for their preparations and their uses. The current invention is to provide an oil-in-water emulsion used as a shampoo additive composition that will help hair care application for shine as well as easy manageability and alignment along with conditioning benefits. The emulsion having a D50 particle size less than 3 micrometers comprising a silicone fluid, a mixture of non-ionic emulsifier； and water, wherein, the silicone fluid is of viscosity of at least 4500 mPa·s at 25° C.
