The present disclosure provides a system and method for a fiber-coupled, metal-tip chemical imaging spectroscopy. The system couples the electromagnetic radiation (EMR), such as laser light, through an optical fiber to a conductive tip for both EMR excitation to the sample through the conductive tip and EMR signal collection from the sample through the conductive tip. The system and method effectively eliminates the need for an optical alignment between the EMR source and the tip, and still offers the customary spatial resolution of a non-coupled system.