PROBLEM TO BE SOLVED: To provide a fluorine insolubilizing agent which can show excellent fluorine insolubilizing effect even on a fluorine-containing material that contains iron or aluminum in relatively high concentrations.SOLUTION: A fluorine insolubilizing agent comprises dibasic calcium phosphate dihydrate, hydroxyapatite, and gypsum so that the total amount of dibasic calcium phosphate dihydrate and hydroxyapatite is 99-30 mass% and gypsum is 1-70 mass% (the total amount of them is 100 mass%).SELECTED DRAWING: None