A process providing a method to create 3D scaffolds using nano-scale fibers, comprising: deposition and alignment of a plurality of electrospun fiber layers on a substrate application of a photosensitive biomedical polymer liquid to each fiber layer deposited on said substrate deposition and cross-alignment of a plurality of electrospun fiber layers on said substrate retaining said polymer liquid in place using said cross-aligned fiber layers curing said polymer liquid on top of each fiber layer using UV light.