PROBLEM TO BE SOLVED: To provide a liquid surfactant composition that contains a polyoxyalkylene alkyl ether sulfate ester salt with a predetermined branching fraction in high concentration and is excellent in stability.SOLUTION: The surfactant composition contains (a) 40-58 mass% mixture of a compound represented by general formula (1): RO(AO)nSO3M, in the mixture the ratio of a compound, of which R in general formula (1) is a hydrocarbon group having a branched chain, is 15 mass% or higher and not higher than 50 mass%, (b) 10-20 mass% at least one kind of a 1-6C lower alcohol, and (c) 22-50 mass% water. In general formula (1), R is a 9-24C hydrocarbon group having a linear or branched chain A is a 2-4C alkylene group M is an alkali metal or the like and n is such a number that its mean value in component (a) is 0-100.COPYRIGHT: (C)2008,JPO&INPIT【課題】所定分岐率のポリオキシアルキレンアルキルエーテル硫酸エステル塩を高濃度で含有し、且つ安定性にも優れた液状の界面活性剤組成物を提供する。【解決手段】(a)下記一般式(1)で表される化合物の混合物であって、一般式(1)中のRが分岐鎖を有する炭化水素基である化合物の比率が15質量%以上50質量%以下である混合物40~58質量%、(b)炭素数が1~6の低級アルコールの一種以上10~20質量%、及び(c)水22~50質量%を含有する界面活性剤組成物。RO(AO)nSO3M (1)(式中、Rは、直鎖又は分岐鎖を有する炭素数9~24の炭化水素基を示し、Aは炭素数2~4のアルキレン基を示し、Mはアルカリ金属等を表し、nは(a)成分における平均値が0~100となる数を表す。)【選択図】なし