A luminescent coating is disclosed that is used to dimensionally control the curing of a photocurable agent placed in close contact with the coating. The coating is applied at the interface of structures, such as brackets and prosthetics, or may be applied directly on a curable material for use in 3D printing, at the location where bonding material is needed to be cured. The luminescent coating irradiates from its structure the curing radiations necessary to photopolymerize the resin in response to a first radiation irradiated on its structure of a different wavelength.