A composition directed to a rinse-off composition for hair frizz reduction comprising from about 0.2% to about 20.0% of a moisture control material or mixture of moisture control materials wherein the moisture control material is selected from one or more of the following: a) wherein R is hydrogen or metal ion, R6 is methyl, ethyl, propyl, alkenyl or phenyl having less than 12 carbon atoms and wherein R7, R8, R9, R10, R11, R12 are hydrogen, methyl, ethyl, propyl, phenyl, hydroxyl, methoxy or ethoxy groups； b) an alcohol wherein R13 is an alkyl, alkenyl, straight or branched carbon chains and； and wherein R14 is hydrogen, hydroxyl, alkyl, methyl, ethyl and propyl wherein the structure of such alcohol contains less than 20 total carbon atoms； c) alcohol comprising an unsaturated double bond in the C2 position. d) an alkyl-substituted glycol wherein the structure of such alkyl substituted glycol contains less than 20 carbon atoms； e) a monoalkyl or dialkyl substituted glycerin or mono- or di-esters of glycerin with fatty acids wherein the structure of such monoalkyl- or dialkyl-substituted glycerin or glycerin esters contains less than 20 total carbon atoms； f) wherein R15 could be hydrogen, alkyl, alkenyl, phenyl group and wherein the structure of the R13 group contain less than 20 carbon atoms； g) a fatty acid ester containing from 15-40 total carbon atoms and wherein the moisture control material is weakly to non-acidic and further wherein the moisture control material has protein binding higher than 10 and molecular volume lower than 1500 and log P higher than 0.5 and pKa of 5 or higher and hydrogen-binding higher than 4 and at least about a 4% frizz reduction vs. control composition without the moisture control materials.
