FIELD: chemistry.SUBSTANCE: invention relates to compositions for preventing caking for solid fertilizers, their use and method for producing solid fertilizers resistant to caking. Anti-caking composition comprises component (a) which comprises a mixture of mono-, di- or tri-esters of quaternary ammonium compounds; and a component (b) comprising a solvent. Solvent is selected from the group consisting of mineral oils, paraffins and waxes derived from vegetable and animal fats and oils. Solvent content is 50 % by weight or more, based on the total weight of the composition.EFFECT: composition is provided that has improved characteristics to prevent caking and dust formation, stability and improved rheological characteristics when the temperature changes.12 cl, 5 tbl, 12 ex