A solid W/O stable composition comprising a gellifing system comprising at least one hydrophobic gelling agent and at least one hydrophilic gelling agent and an emulsifying system comprising at least one surfactant having HLB value of 14 or less. Further there is disclosed a method of treatment keratinous surface with the inventive composition.本發明係有關一種包含膠凝化體系之固體W/O穩定組合物,係含有:至少一種疏水性膠凝劑與至少一種親水性膠凝劑、及包含至少一種具有HLB值為14或更少之界面活性劑的乳化系統。再者本發明揭示以本發明組合物治療角質表面之方法。