The present invention discloses preservative-free toothpaste for children. The composition forming the preservative-free toothpaste for children consists of vitamin, calcium glycerophosphate, xylitol, sorbitol, polyethylene glycol, cellulose, hydroxypropyl guar gum, sodium lauryl sulfate, flavors and deionized water. The composition contains, by weight percentage, 0.01-0.06% of vitamin, 0.1-0.5% calcium glycerophosphate and 0.1-1% of xylitol. The vitamin comprises both vitamin E and vitamin C. In the present invention, vitamin E, vitamin C, calcium glycerophosphate and xylitol are combined in a certain proportion. The vitamin nourishes the children's tender gums. The calcium glycerophosphate provides calcium supplementation to the teeth. The xylitol has a reduced content of sugar, which prevents tooth decay and strengthens the teeth.