A dental care product comprising carbonate-substituted fluoro-hydroxyapatite particles having the formula: Ca(10-z-y-m)ZnxSryMm(PO4)(6-z)(CO3)z(OH)2-wFw wherein M is selected from the group comprising Mg, Se, K and mixtures thereof x is a number comprised between 0 and 0.02 y is a number comprised between 0.0010 and 0.015 m is a number between 0 and 0.5 z is a number comprised between 0.0010 and 0.010 and w is a number comprised between 0.000002 and 0.0001 wherein said fluoro-hydroxyapatite particles have a crystallinity degree CD comprised between 50 and 85%.
