A starchy container structure having a silicone layer, comprising: a starchy container, mainly made of starchy material; an outer layer of silicone, attached to the surface of the starchy container; wherein the outer layer of the silicone is used to make The starchy container that could not be waterproofed can produce a short-term waterproofing effect; in addition, the outer layer of the silicone rubber and the starchy container can be naturally decomposed without polluting the environment; and the reuse rate is also increased; The container structure can be used more often; on the one hand, the cost of use is reduced, and the damage to the environment is also reduced. The outer layer of the silicone rubber in this case can withstand temperatures above 250 ° C, so it can be used in environments requiring high temperatures, especially for medical use. Therefore, this case can meet the requirements of environmental protection at the same time and be applied in a high temperature environment.