The invention relates to an edible multilayer material, a relative production method and a packaging method with the material. The material comprises: a first layer obtainable by reaction of: a first dispersion which is colloid, aqueous, edible and comprising: a first hydrocolloid substance and, optionally, a food additive and/or a probiotic, with a cation of a bivalent metal selected from a group consisting of calcium, magnesium, strontium and zinc； a second layer, obtainable by reaction of the cation with a second dispersion which is colloid, aqueous, edible and comprising: a compound selected from a group consisting of: the second hydrocolloid substance； cellulose； an edible wax and an edible resin, the second dispersion optionally comprising a food additive and/or a probiotic； and a third edible layer, obtainable by reaction of the cation with a third dispersion which is colloid, aqueous, edible and comprising: a single third hydrocolloid substance and, optionally, a food additive and/or a probiotic； wherein the first hydrocolloid substance and the third hydrocolloid substance are different to one another and to the second hydrocolloid substance when this latter is present.
