WARD, ROBERT S.,MCCREA, KEITH R.,TIAN, YUAN,PARAKKA, JAMES P.,WANG, SHANGER
申请号：
CA2630099
公开号：
CA2630099C
申请日:
2006.12.07
申请国别(地区):
CA
年份:
2014
代理人:
摘要：
Polymers having the formula R(LE)x wherein R is a polymeric core having anumber average molecular weight of from 5000 to 7,000,000 daltons and having xendgroups, E is an endgroup covalently linked to polymeric core R by linkageL, L is a divalent oligomeric chain, having at least 5 identical repeat units,capable of self-assembly with L chains on adjacent molecules of the polymer,and the moieties (LE)x in the polymer may be the same as or different from oneanother. Design of monomers, oligomers, or other reactive structures otherwiseanalogous to known Self Assembled Monolayers but with at least one reactivechemical group capable of binding them to the terminus of a polymer, so thatthe thiol-free SAM analogue becomes the self-assembling surface modifyingendgroup of that polymer. Use of the polymer to fabricate a configured articlefrom the surface-modified polymer or a coating or topical treatment on anarticle made from another material.
