A masticatory orthodontic device includes a masticatory unit with a rigid body. The masticatory unit is configured to be removably worn on a dental arch, wherein when worn during mastication, the shape of the masticatory unit is maintained even under a stress from occlusal forces. The masticatory unit includes a teeth-receiving surface with several recesses for accommodating teeth of the dental arch. A shape memory mesh is disposed between the teeth-receiving surface and the dental arch, configured to remember the shape of the teeth in target teeth positions to guide teeth movements from initial teeth positions toward the target teeth positions. A buffering member is disposed between the teeth-receiving surface and the shape memory mesh. Occlusal forces loading on the masticatory unit are transmitted to the shape memory mesh and the teeth through the buffering member, to achieve teeth movements in the recesses.