Балазовский Марк Борисович (RU),Антонов Виктор Георгиевич (RU),Беляев Александр Николаевич (RU),Еремин Алексей Владимирович (RU)
申请号：
RU2010132727/15
公开号：
RU2010132727A
申请日:
2009.02.16
申请国别(地区):
RU
年份:
2012
代理人:
摘要：
1. A composition containing bi- or oligonuclear coordination compounds in an aqueous solution formed by the same or different d-metal atoms linked by one or more bridging groups and containing water molecules and / or hydroxide in the internal sphere of each d-metal atom groups, as well as labile ligands, which are easily replaced by sulfur atoms of thioamino acids or peptides, such as mono-, bi-, or higher-dentate organic molecules with bridging and non-bridging types of coordination to d-metal atoms s. ! 2. The composition according to claim 1, where the atoms of the d-metal (d-metals) in the coordination compound are linked by one or more bridging oxo and / or hydroxo groups. ! 3. The composition according to claim 1, containing in an aqueous solution binuclear coordination compounds formed by d-metal atoms linked together by one or more bridge groups, and containing water molecules and / or hydroxide groups in the inner sphere of each d-metal atom, as well as labile ligands that are easily replaced by sulfur atoms of thioamino acids or peptides. ! 4. The composition according to claim 3, where the specified binuclear compound has a skeleton selected from the group comprising the skeletons of the following formulas:! ! 5. The composition according to claim 1, containing in the composition of the inner sphere of each d-metal atom tightly bound ligands of any nature and dentality with bridge and non-bridge types of coordination to d-metal atoms. ! 6. The composition according to claim 1, where labile ligands are oxygen-containing and / or nitrogen-containing and / or sulfur-containing organic molecules. ! 7. The composition according to claim 1, where the concentration of d-metal (d1. Композиция, содержащая в водном растворе би- или олигоядерные координационные соединения, образованные одинаковыми или разными атомами d-металлов, связанными между собой одной или несколькими мостиковыми группами, и содержащие в составе внутренней сферы каждого атома d-металла молекул
