A method and system for fumigating a material is disclosed. The method includes the steps of containing the material to be fumigated in a containment volume and forming a gas mixture in the containment volume, the gas mixture including at least a fumigation agent and an ambient gas originally present within the containment volume, wherein the partial pressure of the fumigation agent is elevated with respect to the ambient gas in the containment volume. The method further includes then maintaining a concentration of a fumigation agent within the containment volume for a required time to fumigate the material and then removing the fumigation agent from the containment volume.