DANIEL FRICKER,HARALD PLÖCHINGER,MARC HAGER,RICHARD WALTHER
申请号:
BR112014017054
公开号:
BR112014017054B1
申请日:
2012.12.14
申请国别(地区):
BR
年份:
2019
代理人:
摘要:
The invention refers generally to a process for the preparation of water -absorbing polymeric particles, comprising the process steps of: (i) preparation of an aqueous solution of monomer induction Monoethylenically neutralised monoethylene unsaturated mono -mers having acid groups (a1) and at least one reticulation agent (a3);(ii) optional addition of fine particles of a water -absorbing polymer or saline aqueous solutions to the monomer aqueous solution; (iii) addition of a polymerisation initiator or or of at least one component of a polymerisation initiation system comprising two or more The components to the monomer aqueous solution; (iv) oxygen depletion of the monomer aqueous solution; (v) supply of the monomer aqueous solution in a polymerisation reactor; (vi) polymer polymer in the monomer aqueous solution in a polymer reactor Action;(vii) discharge of the polymer gel plate out of the polymerisation reactor and optionally fragmentation of the material then obtaining polymer gel particles; (viii) drying of polymer gel particles; (ix) grinding of dry polymer gel particles Ground water -absorbing polymer ulas; (x) classification by size of the ground particles of water -absorbing polymer; and (xi) reticulation of the surface of the water -absorbing and classified polymer particles; where the process step (xi) comprises steps (d) And: (xia) mixing of particles with aqueous solution of the reticulation agent;And (xib) heat treatment of the mixture obtained at the process stage (xia) in a horizontally operated mixing equipment; where the horizontal mixing equipment operated is hydraulically triggered.processo para o preparo de partículas poliméricas absorvedoras de água a invenção é referente genericamente a um processo para a preparação de partículas poliméricas absorvedoras de água, compreendendo as etapas de processo de: (i) preparo de uma solução aquosa de monômero compreendendo monômeros pelo menos parcialmente neutralizados insaturados monoetilenicamente po