Provided are cosmetic compositions capable of forming a multilayer structure after application to a keratinous material. Certain compositions comprise about 1% to 90% by weight with respect to the total weight of the composition of water； about 5% to 60% by weight with respect to the total weight of the composition of Component A which comprises at least one silicone- and/or hydrocarbon-containing film forming agent having at least one glass transition temperature which is lower than normal human body temperature； and about 0.01% to 90% by weight with respect to the total weight of the composition of Component B which comprises one or more silicone compounds in amounts sufficient to achieve a viscosity of about 1,000 cSt to 22 million cSt, wherein the weight ratio of the silicone- and/or hydrocarbon-containing film forming agent(s) in Component A to silicone compound(s) in Component B is from about 1:50 to 50:1.
