A process of styling hair involving applying onto the hair a composition containing: (a) at least one propylphenylsilsesquioxane resin comprising from about 30 to about 50 mole % of propyl siloxy units, based on the total mole % of siloxy units of the resin, and from about 50 to about 70 mole % of phenyl siloxy units, based on the total mole % of siloxy units of the resin (b) at least one phenylsilsesquioxane resin (c) at least one volatile solvent and (d) optionally, at least one cosmetically-acceptable aromatic solvent.