The present invention relates to a bleaching composition containing, in order to maximize catalytic effects of photocatalytic substances and stability of hydrogen peroxide, a nonionic surfactant in addition to a composition consisting of a hydrogen peroxide-containing compound and titanium dioxide as the photocatalytic substance. The present invention further relates to a dental bleaching method using light which has the wavelength of 455 nm and is emitted from a light-emitting device (LED), by using the bleaching composition.본 발명은 과산화 수소 함유 화합물과 광촉매 물질로서 이산화 티탄을 함유하는 조성물 중에서 과산화수소의 안정성과 광촉매 물질의 촉매 효과를 극대화하기 위해 비이온 계면활성제를 포함시킨 미백 조성물과 이를 사용하여 455nm의 엘이디 빛에 의한 치아 미백 방법에 관한 것이다.