An adjuvant composition containing a) one or more alkyl glucamides of the formula (I), wherein R1 represents a linear or branched alkyl group having 5 to 9 carbon atoms, R2 represents an alkyl group having 1 to 3 carbon atoms; b) at least one water-soluble ammonium salt, preferably selected from the group consisting of ammonium sulfate, ammonium nitrate, ammonium nitrate urea, ammonium phosphate, ammoniumeitrate, ammonium chloride, and ammonium thiosulfate; c) propylene glycol, dipropylene glycol, mixtures of propylene glycol and dipropylene glycol, in each case optionally in a mixture with polypropylene glycol and/or polyethylene glycol, in each case with up to 10 repeating units; and d) water is suitable for increasing the efficacy of electrolyte active substances.