The present invention relates to an enantioselective process for the preparation of trans-5-chloro-2,3,3a,12b-tetrahydro-2-methyl-lH-dibenz[2,3:6,7]oxepino[4,5-c]pyrrole-l-one with an improved yield and quality. Trans-5-chloro-2,3,3a,12b-tetrahydro-2-methyl-lH-dibenz[2,3:6,7]oxepino[4,5-c]pyrrole-l-one is useful intermediate for the preparation of Asenapine and pharmaceuticals acceptable salt.